Organic Letters · 2013 · 35 citations · 32 references
Natural SciencesChemistryCatalysisCatalytic MechanismsCross-coupling ReactionsReaction MechanismsRetrosynthetic AnalysisC - H Activation Cross-couplingCross CouplingCross-coupling CatalysisDouble BondsIntramolecular CatalysisOxidative Cross-couplingTransition-metal-catalyzed Cross-coupling
Unprecedented constructions of C═C double bonds have been achieved by Ir-catalyzed intramolecular dehydrogenative and dehydrative cross-coupling of tertiary amines and ketones. The reactions are proposed to proceed via an Ir-mediated C-H activation mechanism.
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The Atom Economy—A Search for Synthetic Efficiency
The Catalytic Amination of Alcohols
Sebastian Bähn, Sebastian Imm, Lorenz Neubert et al. · ChemCatChem · 2011 · 739 citations