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Beckmann Rearrangements/Allylsilane Cyclizations: Approach to the Pentacyclic Cephalotaxine-Framework and the Influence of the Terminating Silicon Group
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1994
Year
Combinatorial ChemistryMedicinal ChemistrySilicon GroupTandem ReactionsBiochemistryEngineeringNatural SciencesTerminating Silicon GroupBeckmann Rearrangements/allylsilane CyclizationsHeterocyclicOrganic ChemistryChemistryHeterocycle ChemistryPentacyclic Cephalotaxine-frameworkSynthetic ChemistryEnantioselective SynthesisBiomolecular EngineeringInteresting Products
In connection with our studies of tandem reactions to construct heterocyclic systems we report the syntheses of several 7- and 8-membered N-heterocyclic systems leading to pharmacologically interesting products. In addition, the influence of the terminating silicon group has been studied.