X-ray Crystal and NMR Structure of a Highly Reactive Bidentate 1,2-Diamine−OsO<sub>4</sub> Complex, Formally a 20-Electron Outer Valence Shell Species. Mechanistic Implications for the 1,2-Diamine-Accelerated Dihydroxylation of Olefins by OsO<sub>4</sub>

E. J. Corey, Sepehr Sarshar, Mihai Azimioara, Ronald C. Newbold, Mark C. Noe

Journal of the American Chemical Society · 1996 · 73 citations · 10 references

Concepts

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTX-ray Crystal and NMR Structure of a Highly Reactive Bidentate 1,2-Diamine−OsO4 Complex, Formally a 20-Electron Outer Valence Shell Species. Mechanistic Implications for the 1,2-Diamine-Accelerated Dihydroxylation of Olefins by OsO4E. J. Corey, Sepehr Sarshar, Mihai D. Azimioara, Ronald C. Newbold, and Mark C. NoeView Author Information Department of Chemistry, Harvard University Cambridge, Massachusetts, 02138 Cite this: J. Am. Chem. Soc. 1996, 118, 33, 7851–7852Publication Date (Web):August 21, 1996Publication History Received20 February 1996Published online21 August 1996Published inissue 1 January 1996https://pubs.acs.org/doi/10.1021/ja960536dhttps://doi.org/10.1021/ja960536drapid-communicationACS PublicationsCopyright © 1996 American Chemical SocietyRequest reuse permissionsArticle Views967Altmetric-Citations66LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (2)»Supporting Information Supporting Information SUBJECTS:Chemical structure,Hydrocarbons,Ligands,Mathematical methods,Organic compounds Get e-Alerts

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