Concepedia

SO-Photoextrusion of 7-Thiabicyclo[2.2.1]hept-2-ene 7-Oxides

Carolin Thiemann, Thies Thiemann, Yuanqiang Li, Tsuyoshi Sawada, Yoshiaki Nagano, Masashi Tashiro

Bulletin of the Chemical Society of Japan · 1994 · 18 citations · 11 references

DOI

Concepts

Abstract

Abstract The photoextrusion of the SO-bridge of 7-thiabicyclo[2.2.1]hept-2-ene 7-oxides is discussed. An analysis of all the major by-products in the exemplary case of the photo reaction of 3a is given. The existence of intermediate dienes 4 has been established. Data on a comparative photoextrusion of an epithio-bridge of 7-thiabicyclo[2.2.1]-hept-2-ene (6) are provided.

References

11

π-Facial diastereoselectivity in Diels-Alder reactions of 2,5-dimethylthiophene oxide

Arvin Mark Naperstkow, John B. Macaulay, M. J. Newlands et al. · Tetrahedron Letters · 1989 · 65 citations

, , +4

Sulfur monoxide chemistry. Stereochemistry of the thiirane oxide-diene reaction

Peter. Chao, David M. Lemal · Journal of the American Chemical Society · 1973 · 59 citations

, , +5

Sulfur oxide: Low-lying bound molecular electronic states of SO

William C. Swope, Yuan‐Pern Lee, Henry F. Schaefer · The Journal of Chemical Physics · 1979 · 50 citations

, , +16

Sulfur monoxide chemistry. Nature of sulfur monoxide from thiirane oxide and the mechanism of its reaction with dienes

David M. Lemal, Peter. Chao · Journal of the American Chemical Society · 1973 · 47 citations

, , +7

Sulfur Monoxide as 4‐Electron Bridge‐Ligand in the Complex [{(η<sup>5</sup>‐C<sub>5</sub>H<sub>5</sub>)(CO)<sub>2</sub>Mn}<sub>2</sub>SO]

Ingo‐Peter Lorenz, Johannes Messelhäuser, Wolfgang Hiller et al. · Angewandte Chemie International Edition in English · 1985 · 47 citations

, , +12