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Catalytic Enantioselective Synthesis of Adociacetylene B
77
Citations
12
References
2006
Year
Proline-derived LigandNovel OrganocatalystsAsymmetric Zinc AlkynylationEngineeringOrganic ChemistryOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryCatalytic Enantioselective SynthesisAsymmetric CatalysisEnantioselective SynthesisBiomolecular EngineeringAdociacetylene B
A catalytic enantioselective total synthesis of adociacetylene B (2) in five steps is reported. The efficiency of this synthesis was enabled by an asymmetric zinc alkynylation catalyzed by the proline-derived ligand (1).
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