Journal of the American Chemical Society · 2005 · 246 citations · 19 references
Natural SciencesChemistryCatalysisCatalyst DesignCatalyst PreparationCatalyst SynthesisCatalytic MechanismsMetal CatalysisOrganic SynthesisAldehydesAsymmetric CatalysisAsymmetric SynthesisBimetallic Catalyst DesignCatalytic SynthesisDinuclear Metal CatalysisEnantioselective CatalysisEnantioselective Synthesis
Our recent development of a proline-derived bimetallic catalyst has led to a number of efficient, catalytic, enantioselective transformations. Herein, we report a practical and general alkynylation of aromatic and alpha,beta-unsaturated aldehydes using our zinc catalyst system.
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