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Synthesis of Hydroxylated Pyrrolizidines Related to Alexine using Cycloaddition Reactions of Functionalized Cyclic Nitrones
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2004
Year
Natural Product SynthesisEngineeringHydroxylated Pyrrolizidines 6Functionalized δ1-Pyrroline-n-oxides 10HeterocyclicNatural Products AlexineOrganic ChemistryChemistryHydroxylated Pyrrolizidines RelatedHeterocycle ChemistryPharmacologySynthetic ChemistryBiomolecular EngineeringCycloaddition ReactionsFunctionalized Cyclic Nitrones
Cycloaddition reactions of the functionalized Δ1-pyrroline-N-oxides 10 and 19 have been used to prepare the hydroxylated pyrrolizidines 6 and 7 respectively, which are related to the natural products alexine and australine.