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Effects of Subjoin Lewis Acid on the Catalytic Asymmetric Allylic Transfer Reactions of Aldehydes Promoted by BINOL-Ti(IV) Complex
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1997
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Chemical EngineeringCross-coupling ReactionEngineeringAldehydes PromotedAchiral AldehydesSubjoined Lewis AcidOrganic ChemistryOrganometallic CatalysisCatalysisTin ReagentsChemistryMolecular CatalysisSubjoin Lewis AcidAsymmetric CatalysisEnantioselective Synthesis
Practical and efficient catalytic asymmetric allylic transfer reactions of achiral aldehydes with tin reagents promoted by BINOL-Ti(IV) complex are achieved with high enantioselectivity by the utilization of subjoined Lewis acid, B(OMe)3.