A Bridgehead Carbocation Fragmentation Leading to the Taxane AB Ring System

George A. Kraus, Deye Zheng

Synlett · 1993 · 21 citations · 0 references

Concepts

Abstract

The AB ring system was constructed from cyclohexane-1,3-diones by a direct route. The key steps included an intramolecular photocyclization and a fragmentation of a bridgehead carbocation.