Liebigs Annalen der Chemie · 1992 · 11 citations · 15 references
Natural SciencesChemistryMedicinal ChemistryOrganic ChemistrySynthetic Medicinal ChemistryHeterocycle SynthesisHeterocyclic ChemistryOrganic SynthesisRetrosynthetic AnalysisTerpenoid BiosynthesisNatural Product Total SynthesisRing-forming ReactionsSesquiterpene BiosynthesisTotal Synthesis-derived Analogues
Abstract rac ‐Sesquiterpenoid AE 1 ( rac ‐ 1 ) can be obtained in an 11‐step sequence starting from 5‐methylresorcinol ( 2 ). The key compound 9 is synthesized by the use of a diastereoselective dienone cyclization with the allylic silane 8 . Subsequent transformation of 9 leads to rac ‐ 1 .
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Intramolecular Addition Reactions of Allylic and Propargylic Silanes
Dieter Schinzer · Synthesis · 1988 · 160 citations