Cross-coupling of arylboronic acids with terminal alkynes in air

A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes and bromopyridines

Kenkichi Sonogashira, Yasuo Tohda, Nobue Hagihara · Tetrahedron Letters · 1975 · 5.1K citations

Chemical Engineering, Catalytic Substitutions, Engineering +8

Acetylenic Coupling: A Powerful Tool in Molecular Construction

Peter Siemsen, R. C. Livingston, François Diederich · Angewandte Chemie International Edition · 2000 · 1.5K citations

Cross-coupling Reaction, Enantioselective Synthesis, Engineering +13

Molecular Electronics. Synthesis and Testing of Components

James M. Tour · Accounts of Chemical Research · 2000 · 1.3K citations

Engineering, Nanotechnology, Nanonetwork +9

Improved Procedures for the Palladium-Catalyzed Coupling of Terminal Alkynes with Aryl Bromides (Sonogashira Coupling)

Stephan Thorand, Norbert Krause · The Journal of Organic Chemistry · 1998 · 352 citations

Palladium-catalyzed Coupling, Terminal Alkynes, Cross-coupling Reaction +8

Transmetalation of Palladium Enolate and Its Application in Palladium-Catalyzed Homocoupling of Alkynes:  A Room-Temperature, Highly Efficient Route To Make Diynes

Aiwen Lei, Manisha Srivastava, Xumu Zhang · The Journal of Organic Chemistry · 2002 · 187 citations

Chemical Engineering, Cross-coupling Reaction, Engineering +14