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Synthesis of [m,7,n]-Tricycles via Platinum-Catalyzed Cyclization of Conjugated Enynals with a Pendant Alkene
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2007
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Active Natural ProductsEngineeringHeterocyclicBiochemistryAlkene MetathesisNatural SciencesPendant AlkeneOrganic ChemistryOrganometallic CatalysisCatalysisConjugated EnynalsChemistryPlatinum CatalystsValuable SkeletonsNatural Product SynthesisEnantioselective SynthesisBiomolecular EngineeringPlatinum-catalyzed Cyclization
Conjugated enynals anchored to cycloalkenes, in the presence of platinum catalysts, were cyclized to the corresponding [m,7,n]-tricarbocycles, which are valuable skeletons in biologically active natural products like taxoids.