Hydrogen sulphide detection using near-infrared diode laser and compact dense-pattern multipass cell*

Abstract

Sub-ppmv level detection of hydrogen sulphide (H 2 S) using a 1.578- <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <mml:mi mathvariant="normal">μ</mml:mi> <mml:mi mathvariant="normal">m</mml:mi> </mml:math> distributed feedback tunable diode laser combining with wavelength modulation spectroscopy and second harmonic detection scheme is reported. A home-developed novel compact dense-pattern multipass gas cell with an effective optical path length of 29.37 m is used to improve sensitivity and reduce sample volume. Detection parameters are optimized, including modulation frequency and amplitude. The analysis of Allan variance shows that a minimum detectable concentration 60 ppbv is obtained with a lock-in time constant of 10 ms, and a detection limit of 13 ppbv can be achieved by average in 300 s. The demonstrated H 2 S sensor has a strong penitential application in natural gas process for regulating and controlling H 2 S concentration.