The Journal of Physical Chemistry B · 2019 · 86 citations · 25 references
Natural SciencesChemical EngineeringChemistryMaterials ChemistryNanomaterialsPhysical ChemistrySolution ChemistryWater ChemistryCholine Chloride-based SolventsDeep Eutectic SolventsMedia Physical PropertiesPhysical PropertiesSolvent Effects On SpectraSolvent Interactions
Deep eutectic solvents (DESs) have potential as designer media whose physical, chemical, electrochemical, and spectroscopic properties are easily and broadly tuned. Due to the ubiquity of water and the hygroscopic nature of many DES components, it is important to understand how water affects DESs both on the nanoscale and in the bulk. Here, we present a study of the physical properties of DES/water mixtures. We found that water appears to form a ternary DES when mixed with 2:1 urea/ChCl.
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Andrew P. Abbott, Glen Capper, David L. Davies et al. · Chemical Communications · 2002 · 5.5K citations · Full text