Rational Construction of Breathing Metal–Organic Frameworks through Synergy of a Stretchy Ligand and Highly Variable π–π Interaction

Ying Zhang, Xiaoqing Meng, Hao-Jing Ding, Xi Wang, Mei‐Hui Yu, Shu-Ming Zhang, Ze Chang, Xian‐He Bu

ACS Applied Materials & Interfaces · 2019 · 28 citations · 51 references

Concepts

Abstract

) sorption, which was verified by stepwise sorption isotherms and in situ powder X-ray diffraction. Additional investigation of the sorption selectivity of C3/C2 systems indicated that the selectivity can be regulated by the modulation of the dynamic breathing behaviors, which can be used for the selective separation of C3/C2 light hydrocarbons.

References

51