Accelerated Degradation of Thiocarbamate Herbicides in Soil with Prior Thiocarbamate Herbicide Exposure

Abstract

Laboratory studies were conducted to evaluate the degradation of butylate ( S -ethyl diisobutylthiocarbamate), EPTC ( S -ethyl dipropylthiocarbamate), cycloate ( S -ethyl N -ethylthiocyclohexanecarbamate), and vernolate ( S -propyldipropylthiocarbamate) in soil with prior thiocarbamate herbicide exposure. EPTC degradation was accelerated in soil which had previously been treated with butylate, vernolate, or EPTC in 1979, 1980, and 1981. The evolution rate of 14 CO 2 from 14 C-labeled vernolate was increased in soil which had previously been treated with vernolate or EPTC in 1979, 1980, and 1981. Cycloate degradation was not enhanced in soil with prior exposure to butylate, EPTC, or vernolate. Butylate breakdown was enhanced to the greatest extent in soil with previous exposure to butylate.