Topological Disentanglement Dynamics of Torus Knots on Open Linear Polymers

Abstract

We simulate and study the topological disentanglement occurring when torus knots reach the ends of a semiflexible open polymer (decay into simpler knots or unknotting). Through a rescaling procedure and the application of appropriate boundary conditions, we show that the full unknotting process can be understood in terms of point-like particles representing essential crossings, diffusing on the support [0, 1]. We address the bending and configurational free energy drives on the diffusion process, together with the scaling properties of the effective diffusion and friction coefficients. Agreement with simulations suggests universal features for these two model parameters.