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The formation mechanism of TiO<sub>2</sub> polymorphs under hydrothermal conditions based on the structural evolution of [Ti(OH)<sub>h</sub>(H<sub>2</sub>O)<sub>6−h</sub>]<sup>4−h</sup> monomers
51
Citations
17
References
2019
Year
EngineeringHydrolysis RatioInorganic PhotochemistryChemistryInorganic MaterialPolymersStructural EvolutionThermal CatalysisHydrothermal SynthesisMaterials ScienceInorganic ChemistryFormation MechanismHydrothermal ConditionsFunctional MaterialsCatalysisTitanium Dioxide MaterialsCondensation ReactionChemical KineticsHydrothermal Processing
In the hydrothermal synthesis of TiO<sub>2</sub>, [Ti(OH)<sub>h</sub>(H<sub>2</sub>O)<sub>6−h</sub>]<sup>4−h</sup> (<italic>h</italic> is the hydrolysis ratio) monomers are generated by the dissolution of the precursor containing titanium ions and then, the monomers form TiO<sub>2</sub> polymorphs <italic>via</italic> a condensation reaction.
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