Facile Synthesis of BiVO₄ for Visible‐Light‐Induced C−C Bond Cleavage of Alkenes to Generate Carbonyls

Abstract

BiVO₄ crystals synthesized by an ultrasonic-assisted method (Sono-BiVO₄ ) showed improved efficiency as a heterogeneous photocatalyst under visible-light irradiation. Sono-BiVO₄ was successfully used for the C-C bond cleavage of alkenes to generate carbonyl compounds. Styrene derivatives were converted into carbonyl compounds in the presence of Sono-BiVO₄ under highly sustainable conditions requiring only natural sources, that is, molecular oxygen, visible light, and water at room temperature. Additionally, Sono-BiVO₄ could be easily separated from the reaction mixture and reused.