A Hydride Route to Ternary Alkali Metal Borides: A Case Study of Lithium Nickel Borides

Abstract

Abstract Ternary lithium nickel borides LiNi 3 B 1.8 and Li 2.8 Ni 16 B 8 have been synthesized by using reactive LiH as a precursor. This synthetic route allows better mixing of the precursor powders, thus facilitating rapid preparation of the alkali‐metal‐containing ternary borides. This method is suitable for “fast screening” of multicomponent systems comprised of elements with drastically different reactivities. The crystal structures of the compounds LiNi 3 B 1.8 and Li 2.8 Ni 16 B 8 have been re‐investigated by a combination of single‐crystal X‐ray/synchrotron powder diffraction, solid‐state 7 Li and 11 B NMR spectroscopies, and scanning transmission electron microscopy. This has allowed the determination of fine structural details, including the split position of Ni sites and the ordering of B vacancies. Field‐dependent and temperature‐dependent magnetization measurements are consistent with spin‐glass behavior for both samples.