Bond theory, terahertz spectra, and dielectric studies in donor‐acceptor (Nb‐Al) substituted ZnTiNb ₂ O ₈ system

Abstract

Abstract As a donor and acceptor separately, Nb 5+ and Al 3+ are used to substitute Ti 4+ in the ixiolite ZnTiNb 2 O 8 system for the first time. The dielectric responses in the terahertz range of this system are initially studied based on the data from terahertz time‐domain transmitted spectroscopy. Combined with ligand field theory, the formation of a secondary phase of ZnAl 2 O 4 is reasonably explicated. Then, the origins of the lower dielectric loss and the terahertz wave absorption coefficient are determined to be the high chemical bond covalency and effective phase control. For the composition of ZnTi 0.85 (Al 0.5 Nb 0.5 ) 0.15 Nb 2 O 8 sintered at 1180°C, a low dielectric loss (<5 × 10 −3 @ 0.5 TH z) and absorption coefficient (<10/cm @ 0.5 TH z) are obtained, which make this kind of material propitious for developing terahertz dielectric devices.