Materials · 2018 · 24 citations · 33 references
Natural SciencesMaterials EngineeringMaterials ScienceMaterials ChemistryOptical MaterialsThin FilmsOrganic Electronic MaterialsOrganic SemiconductorsPhotoelectrochemical MaterialsPhotovoltaic MaterialsSolar Cell MaterialsSolar CellsDye-sensitized Solar CellsMetal-organic Framework Redox MaterialsMetal-organic FrameworksOrganic PhotovoltaicsSolar Cell Device PhysicsSolar Cell FabricationThin-film Solar Cells
Metal–organic framework thin film-based dye sensitized solar cell is fabricated with highly oriented, crystalline, and porous Zn-perylene metal-organic framework (MOF) thin film (SURMOF) which is integrated with Bodipy embedded in poly(methyl methacrylate). It has been demonstrated that the photocurrent can be enhanced by a factor of 5 relative to Zn-perylene MOF thin film due to triplet–triplet annihilation up-conversion between the Bodipy/PMMA sensitizer and the Zn-perylene MOF thin film acceptor using Co(bpy)32+/3+ as redox mediator.
33