Concepedia

Visible Light-Mediated Photocatalytic Metal-Free Cross-Coupling Reaction of Alkenyl Carboxylic Acids with Diarylphosphine Oxides Leading to β-Ketophosphine Oxides

Haifeng Qian, Chengkun Li, Zhihao Zhou, Ze‐Kun Tao, Adedamola Shoberu, Jian‐Ping Zou

Organic Letters · 2018 · 75 citations · 58 references

DOI

Concepts

Abstract

A new visible light-mediated photocatalytic decarboxylative oxyphosphorylation of cinnamic acids with diarylphosphine oxides is described. This reaction is performed under mild conditions to afford the corresponding β-ketophosphine oxides.

References

58

Photoredox Catalysis in Organic Chemistry

Megan H. Shaw, Jack Twilton, David W. C. MacMillan · The Journal of Organic Chemistry · 2016 · 3.1K citations · Full text

, , +14

Donor–Acceptor Fluorophores for Visible-Light-Promoted Organic Synthesis: Photoredox/Ni Dual Catalytic C(sp<sup>3</sup>)–C(sp<sup>2</sup>) Cross-Coupling

Jian Luo, Jian Zhang · ACS Catalysis · 2016 · 843 citations

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Visible-Light-Promoted Selective Oxidation of Alcohols Using a Covalent Triazine Framework

Wei Huang, Beatriz Chiyin, Hao Lü et al. · ACS Catalysis · 2017 · 343 citations

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Metal-Free, Visible Light-Photocatalyzed Synthesis of Benzo[<i>b</i>]phosphole Oxides: Synthetic and Mechanistic Investigations

Valentin Quint, Fabrice Morlet‐Savary, Jean‐François Lohier et al. · Journal of the American Chemical Society · 2016 · 337 citations

, , +16

Palladium-Catalyzed Intermolecular Decarboxylative Coupling of 2-Phenylbenzoic Acids with Alkynes via C−H and C−C Bond Activation

Congyang Wang, Souvik Rakshit, Frank Glorius · Journal of the American Chemical Society · 2010 · 288 citations

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