Use of super absorbent hydrogels derivative from acrylamide with itaconic acid and itaconates to remove metal ions from aqueous solutions

Abstract

ABSTRACT Poly(acrylamide‐ co ‐itaconic acid) (AAm/IA) and poly(acrylamide‐ co ‐monomethoxyethyl itaconate) (AAm/MEI) hydrogels (HGs) synthesized at different molar ratios were used to study the adsorption of some metal ions as Cu 2+ , Ni 2+ , Pb 2+ , Cd 2+ , and Fe 3+ in aqueous solutions at different concentration: 10, 50, 100, 500, and 1000 mg L −1 . Statistical analysis was performed and the effect of the metal ion, ion concentration, and hydrogel (HG) composition, on adsorption and adsorption efficiency, was evaluated for both HGs studied (AAm/IA and AAm/MEI) and each factor gave rise to significant differences ( P ≤ 0.05). The adsorption depends on the type of ion, its concentration, and also influenced by the type and composition of the HGs. For each system the adsorption efficiencies for all ions were similar with exception of Fe 3+ , which showed the highest adsorption efficiency in AAm/MEI HG, but the less for the AAm/IA. For both systems, the maximum adsorption efficiency was observed when the molar ratio AAm/IA or AAm/MEI is 80/20. When the adsorption was carried out with individual ions, AAm/MEI HG was more efficient than AAm/IA. For a multielement sample of Cu 2+ , Ni 2+ , Pb 2+ , and Cd 2+ , both HGs could adsorb all the ions and their behavioral trend was the same in both cases, in which the adsorption efficiency was Pb 2+ > Cu 2+ > Cd 2+ > Ni 2+ . The results of the statistical analysis evidence the advantage of its use in this type of studies. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136 , 46999