A stable polyoxometalate-based porous coordination polymer with high proton conductivity

Abstract

A new porous coordination polymer (<bold>1</bold>) has been prepared by a hydrothermal method. The supramolecular framework of <bold>1</bold> is stable in aqueous solutions with pH ranging from 1 to 13 and boiling solvents, such as water, methanol and ethanol. The proton conductive properties of <bold>1</bold> are also studied.