Chemical Communications · 2018 · 53 citations · 43 references
Natural SciencesChemistryPhysicsCondensed Matter PhysicsCrystal StructureMagnetic MaterialsMagnetic Properties Of SolidsMagnetism In SolidsMagnetism Of Inorganic CompoundsNuclear SpinLanthanide MagnetismLanthanide Single-molecule MagnetsMolecular MagnetismMolecular MagnetsSingle-molecule MagnetismSingle-molecule Magnets
The first triradical bridged binuclear penta-spin single-molecule magnet, [Dy2(hfac)6(BTR)], based on a nitronyl nitroxide triradical was synthesized and characterized. Theoretical calculations revealed Dy-radical antiferromagnetic coupling and radical-radical ferromagnetic coupling. The SMM behavior is found to originate from the exchange states, rather than the isolated Dy3+ center.
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Molecular magnetic hysteresis at 60 kelvin in dysprosocenium
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