Concepedia

Visible light accelerated hydrosilylation of alkynes using platinum–[acyclic diaminocarbene] photocatalysts

Jack C. Gee, Beth A. Fuller, Hannah-Marie Lockett, Gita Sedghi, Craig M. Robertson, Konstantin V. Luzyanin

Chemical Communications · 2018 · 58 citations · 31 references

DOI

Concepts

Abstract

Platinum-[diaminocarbene] complexes work as transition-metal photocatalysts for the hydrosilylation of alkynes. A catalytic system operates under visible light irradiation (blue LED) enabling the conversion of a range of terminal and internal alkynes to respective vinyl silanes in excellent yields.

References

31

Single-Electron Transmetalation via Photoredox/Nickel Dual Catalysis: Unlocking a New Paradigm for sp<sup>3</sup>–sp<sup>2</sup> Cross-Coupling

John C. Tellis, Christopher B. Kelly, David N. Primer et al. · Accounts of Chemical Research · 2016 · 673 citations · Full text

, , +17

Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

Aaron M. Tondreau, Crisita Carmen Hojilla Atienza, Keith J. Weller et al. · Science · 2012 · 543 citations

, , +13

Catalysis by transition metal complexes of alkene silylation–recent progress and mechanistic implications

Bogdan Marciniec · Coordination Chemistry Reviews · 2005 · 451 citations

, , +9

Shining Light on Copper: Unique Opportunities for Visible-Light-Catalyzed Atom Transfer Radical Addition Reactions and Related Processes

Oliver Reiser · Accounts of Chemical Research · 2016 · 394 citations

Suppression of unwanted heterogeneous platinum(0)-catalyzed reactions by poisoning with mercury(0) in systems involving competing homogeneous reactions of soluble organoplatinum compounds: thermal decomposition of bis(triethylphosphine)-3,3,4,4-tetramethylplatinacyclopentane

George M. Whitesides, Marifaith. Hackett, Robert L. Brainard et al. · Organometallics · 1985 · 342 citations

, , +13