Suppression of surface charge on micro- and nano-structured superhydrophobic silicone rubber

Abstract

Laser-ablated template and fluoroalkyl silane modified composite coatings are used to prepare a micro- and nano-structure on silicone rubber surfaces. By testing the surface potential accumulation and dissipation process, we assess the suppression of surface charge on superhydrophobic silicone rubber. The surface physicochemical properties and resistivity are examined. The electron and hole trap distribution are analysed using isothermal current decay theory. Peak density of traps associated with the superhydrophobic surfaces are found to be promoted to lower energy levels relative to unmodified silicone. Surface micro-structure increases trap density and reduce trap depth; nano coatings are shown to further reduce surface trap depth. The improvements shown to suppress surface charge accumulation is beneficial to a range of electrical industries and helps mitigate surface flashover on insulation.