Probing the Evolution of Palladium Species in Pd@MOF Catalysts during the Heck Coupling Reaction: An Operando X-ray Absorption Spectroscopy Study

Ning Yuan, Vlad Paşcanu, Zhehao Huang, Alejandro Valiente, Niclas Heidenreich, Sebastian Leubner, A. Ken Inge, Jakob Gaar, Norbert Stock, Ingmar Persson,

Journal of the American Chemical Society · 2018 · 97 citations · 79 references

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Abstract

ions to their surfaces, which causes the poisoning of the active sites. By understanding the deactivation process, it was possible to tune the reaction conditions and prolong the lifetime of the catalyst.

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