Concepedia

Visible-light photocatalytic trifluoromethylthiolation of aryldiazonium salts: conversion of amino group into trifluoromethylthiol group

Xia Zhao, Xiancai Zheng, Miaomiao Tian, Yifan Tong, Bo Yeun Yang, Xianfu Wei, Di Qiu, Kui Lu

Organic Chemistry Frontiers · 2018 · 39 citations · 35 references

DOI

Concepts

Abstract

A visible-light photocatalytic trifluoromethylthiolation of aryl amine through <italic>in situ</italic> generation of aryldiazonium salts with <italic>S</italic>-trifluoromethyl 4-methoxylbenzenesulfonothioate was developed.

References

35

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Cyclization Cascades via<i>N</i>-Amidyl Radicals toward Highly Functionalized Heterocyclic Scaffolds

Noelia Fuentes, Wangqing Kong, Luis Fernández-Sánchez et al. · Journal of the American Chemical Society · 2015 · 418 citations

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An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation

Xinxin Shao, Xue‐Qiang Wang, Tao Yang et al. · Angewandte Chemie International Edition · 2013 · 414 citations

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Shelf-Stable Electrophilic Reagents for Trifluoromethylthiolation

Xinxin Shao, Chunfa Xu, Long Lü et al. · Accounts of Chemical Research · 2015 · 407 citations

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Pd‐Catalyzed Synthesis of ArSCF<sub>3</sub> Compounds under Mild Conditions

Georgiy Teverovskiy, D. Surry, Stephen L. Buchwald · Angewandte Chemie International Edition · 2011 · 355 citations · Full text

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