Chemistry - An Asian Journal · 2018 · 20 citations · 59 references
Natural SciencesChemistryCatalysisOrganic ChemistryCatalyst DesignCatalyst PreparationCatalyst SynthesisCross-coupling ReactionsOrganic SynthesisNickel CatalysisNickel CatalystsNickel-catalyzed Cross-couplingPalladium CatalystsPalladium-catalyzed Cross-couplingSubstrate ScopeSubstrate Scope Expansion
A decarbonylative C-H coupling of azoles and aromatic esters by palladium catalysis is described. Our previously reported Ni-catalyzed C-H coupling of azoles and aromatic esters has a significant drawback regarding the substrate scope. Herein, we employ palladium catalysis instead of nickel, resulting in a broader substrate scope in terms of azoles and aromatic esters.
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Conversion of amides to esters by the nickel-catalysed activation of amide C–N bonds
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