Transition-metal-free direct trifluoromethylthiolation of electron-rich aromatics using CF3SO2Na in the presence of PhPCl2

Trifluoromethylation of aromatic compounds with sodium trifluoromethanesulfinate under oxidative conditions.

Bernard R. Langlois, E. LAURENT, Nathalie Roidot · Tetrahedron Letters · 1991 · 438 citations

Natural Sciences, Chemistry, Catalysis +2

An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation

Xinxin Shao, Xue‐Qiang Wang, Tao Yang et al. · Angewandte Chemie International Edition · 2013 · 414 citations

Natural Sciences, Chemistry, Organic Chemistry +8

Shelf-Stable Electrophilic Reagents for Trifluoromethylthiolation

Xinxin Shao, Chunfa Xu, Long Lü et al. · Accounts of Chemical Research · 2015 · 407 citations

Pharmacy, Chemistry, Medicinal Chemistry +13

Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Copper-Catalyzed Trifluoromethylthiolation of Enamines, Indoles, and β-Keto Esters

Yudong Yang, Ayaka Azuma, Etsuko Tokunaga et al. · Journal of the American Chemical Society · 2013 · 318 citations

Natural Sciences, Chemistry, Medicinal Chemistry +11

<i>N</i>‐Trifluoromethylthiosaccharin: An Easily Accessible, Shelf‐Stable, Broadly Applicable Trifluoromethylthiolating Reagent

Chunfa Xu, Bingqing Ma, Qilong Shen · Angewandte Chemie International Edition · 2014 · 316 citations

Natural Sciences, Biochemistry, Chemistry +6