Concepedia

How intramolecular hydrogen bonding (IHB) controls the C–ON bond homolysis in alkoxyamines

Gérard Audran, Raphaël Bikanga, Paul Brémond, Mariya Edeleva, Jean‐Patrick Joly, Sylvain R. A. Marque, Paulin Nkolo, Valérie Roubaud

Organic & Biomolecular Chemistry · 2017 · 22 citations · 40 references

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Concepts

Abstract

. For one alkoxyamine, the simultaneous occurrence of IHB within the nitroxyl fragment and between fragments is reported. The protonation effect is weaker in the presence than in the absence of IHB. A moderate solvent effect is also observed.

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