Concepedia

Flexibility in metal–organic frameworks derived from positional and electronic effects of functional groups

Hyeonbin Ha, Hyungwoo Hahm, Dong Gyun Jwa, Kwangho Yoo, Myung Hwan Park, Minyoung Yoon, Youngjo Kim, Min Kim

CrystEngComm · 2017 · 16 citations · 16 references

DOI

Concepts

Abstract

The position of functional groups and the subsequent e-density of the benzene rings in a bi-/tri-functionalized zinc-based metal–organic framework (MOF) have been controlled to reveal structural differences.

References

16

Rigid and Flexible: A Highly Porous Metal–Organic Framework with Unusual Guest‐Dependent Dynamic Behavior

Danil N. Dybtsev, Hyungphil Chun, Kimoon Kim · Angewandte Chemie International Edition · 2004 · 1.2K citations

, , +13

Functionalization in Flexible Porous Solids: Effects on the Pore Opening and the Host−Guest Interactions

Thomas Devic, Patricia Horcajada, Christian Serre et al. · Journal of the American Chemical Society · 2009 · 512 citations

, , +16

How Linker’s Modification Controls Swelling Properties of Highly Flexible Iron(III) Dicarboxylates MIL-88

Patricia Horcajada, Fabrice Salles, Stefan Wuttke et al. · Journal of the American Chemical Society · 2011 · 484 citations

, , +15

Directing the Breathing Behavior of Pillared-Layered Metal–Organic Frameworks via a Systematic Library of Functionalized Linkers Bearing Flexible Substituents

Sebastian Henke, Andreas Schneemann, Annika Wütscher et al. · Journal of the American Chemical Society · 2012 · 465 citations

, , +12

Validity of the <i>t-plot</i> Method to Assess Microporosity in Hierarchical Micro/Mesoporous Materials

Anne Galarneau, François Villemot, Jérémy Rodriguez et al. · Langmuir · 2014 · 344 citations

, , +17