Angewandte Chemie International Edition · 2004 · 1.2K citations · 39 references
Natural SciencesChemistryMaterials ScienceMaterials ChemistryOrganic ChemistrySurface ScienceInorganic MaterialsPorous MaterialsHigh-surface-area MaterialsMetal-organic Framework AdsorptionMetal-organic Framework SynthesisMetal-organic FrameworksPorous Material CharacterizationPorous Material DesignSorption CapacitySurface Area
A large H2 sorption capacity and high surface area are properties of the depicted metal–organic porous material, which is easily synthesized on a large scale from readily available chemicals. The rigid framework of [Zn2(1,4-bdc)2(dabco)] (1,4-H2bdc=1,4-benzenedicarboxylic acid; dabco=diazabicyclo[2.2.2]octane) is also flexible enough to exhibit unusual guest-dependent dynamic behavior, as shown (DMF=N,N-dimethylformamide).
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Design and synthesis of an exceptionally stable and highly porous metal-organic framework
Hailian Li, Mohamed Eddaoudi, M. O’Keeffe et al. · Nature · 1999 · 8.4K citations · Full text