Concepedia

Copper-catalyzed acyltrifluoromethylation of alkenes: rapid access to trifluoroethyl indanones and related compounds

Zhicheng Liu, Yihui Bai, Jian Zhang, Yongqi Yu, Ze Tan, Gangguo Zhu

Chemical Communications · 2017 · 58 citations · 58 references

DOI

Concepts

Abstract

Copper-catalyzed acyltrifluoromethylation of alkenes is described, affording trifluoroethyl indanones and related cyclic ketones in promising yields with excellent diastereoselectivity.

References

58

Visible Light-Mediated Atom Transfer Radical Addition via Oxidative and Reductive Quenching of Photocatalysts

Carl‐Johan Wallentin, John D. Nguyen, Peter Finkbeiner et al. · Journal of the American Chemical Society · 2012 · 967 citations

, , +17

Three‐component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts

Yusuke Yasu, Takashi Koike, Munetaka Akita · Angewandte Chemie International Edition · 2012 · 545 citations

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Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature

Xin Mu, Tao Wu, Haoyang Wang et al. · Journal of the American Chemical Society · 2011 · 486 citations

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Copper-Catalyzed One-Pot Trifluoromethylation/Aryl Migration/Desulfonylation and C(sp<sup>2</sup>)–N Bond Formation of Conjugated Tosyl Amides

Wangqing Kong, Maria Helena Casimiro, Estı́baliz Merino et al. · Journal of the American Chemical Society · 2013 · 444 citations

, , +8

Recent Advances in Trifluoromethylation Reactions with Electrophilic Trifluoromethylating Reagents

Sebastián Barata‐Vallejo, Beatríz Lantaño, Al Postigo · Chemistry - A European Journal · 2014 · 389 citations · Full text

, , +6