Concepedia

Reversible formation and cleavage of Pt→Ag dative bonds in a pre-organized cavity of a luminescent heteropolynuclear platinum(<scp>ii</scp>) complex

Misa Ueda, Shinnosuke Horiuchi, Eri Sakuda, Yoshihide Nakao, Yasuhiro Arikawa, Keisuke Umakoshi

Chemical Communications · 2017 · 24 citations · 26 references

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Concepts

Abstract

A heteropolynuclear complex can reversibly capture an Ag(<sc>i</sc>) ion and release it from the pre-organized cavity by the concerted formation and cleavage of Pt→Ag dative bonds and Ag–C(ipso) bonds, respectively.

References

26

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