Concepedia

Cobalt-catalysed Markovnikov selective hydroboration of vinylarenes

Jingying Peng, Jamie H. Docherty, Andrew P. Dominey, Stephen P. Thomas

Chemical Communications · 2017 · 93 citations · 21 references

DOIFull text

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Concepts

Abstract

A bipyridiyl–oxazoline cobalt catalyst<sup>tBu</sup>BPOCoCl<sub>2</sub>has been developed for the Markovnikov selective hydroboration of vinylarenes using pinacolborane and NaO<sup>t</sup>Bu as the<italic>in situ</italic>activator.

References

21

Hydroborations catalysed by transition metal complexes

I. P. Beletskaya, Andrew Pelter · Tetrahedron · 1997 · 618 citations

, , +9

Catalytic Asymmetric Hydroboration: Recent Advances and Applications in Carbon−Carbon Bond‐Forming Reactions

Cathleen M. Crudden, David Edwards · European Journal of Organic Chemistry · 2003 · 523 citations

, , +13

Bis(imino)pyridine Cobalt-Catalyzed Alkene Isomerization–Hydroboration: A Strategy for Remote Hydrofunctionalization with Terminal Selectivity

Jennifer V. Obligacion, Paul J. Chirik · Journal of the American Chemical Society · 2013 · 381 citations

, , +16

Activation and discovery of earth-abundant metal catalysts using sodium tert-butoxide

Jamie H. Docherty, Jingying Peng, Andrew P. Dominey et al. · Nature Chemistry · 2017 · 311 citations · Full text

, , +14

Iron‐Catalyzed, Atom‐Economical, Chemo‐ and Regioselective Alkene Hydroboration with Pinacolborane

Lei Zhang, Dongjie Peng, Xuebing Leng et al. · Angewandte Chemie International Edition · 2013 · 233 citations

, , +5