Effect of metal loading on catalytic activity and selectivity of ZSM-5 zeolite catalyst in conversion of methanol to olefins and aromatics

Abstract

Effect of ZSM-5 zeolite promotion using potassium, strontium, and cerium metals on conversion of methanol to light olefins and aromatics was investigated. ZSM-5 catalyst was promoted using wet impregnation of metal salts and its activity was tested in methanol to hydrocarbons process under optimum operational condition obtained in our group previously. Zeolite samples were characterized by X-ray powder diffraction, scanning electron microscopy, N2 adsorption-desorption, acid sites distribution, and strength using temperature programmed desorption of NH3. Results showed that presence of these metals could significantly affect acid site distribution and therefore influence the catalyst activity and selectivity to olefins and aromatics.