Organic & Biomolecular Chemistry · 2017 · 10 citations · 45 references
Natural SciencesChemistryCatalysisOrganic ChemistryCatalytic MechanismsOrganic SynthesisRuthenium-catalyzed Coupling
We demonstrated the ruthenium-catalyzed allylic amination of 2,3,3-trifluoroallylic carbonates with several types of amines. The reactions proceeded with several types of amines, and succeeded in obtaining polyfluorinated terminal alkenes possessing branched allylic amines as a single regioisomer.
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