Inorganic Chemistry · 2017 · 81 citations · 28 references
Natural SciencesChemistryMaterials ScienceAnalytical ChemistryBiosensorsSpectroscopyCoordination ChemistryLigand BindingLigand-based DesignMetal-ligand BondingTransition Metal ChemistryTransition Metal ComplexesCoordinationLuminescent Coordination CompoundsLuminescent Metal-organic FrameworksMetal-organic Framework SensorsMetal-organic Framework SynthesisMetal-organic FrameworksRational DesignStimuli-responsive Luminescent Materials
By employing a rational design approach, we synthesized three luminescent metal–organic frameworks (MOFs) 1 – 3 affording different coordination modes of V-shaped thienylpyridyl ligand. Their application in detecting metal ions was explored, and the mechanism was inferred. And the result exhibits that MOF 3 is a dual-responsive luminescent probe for Fe 3+ and Al 3+ ions.
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