Role of the local structure in superconductivity of LaO_0.5F_0.5BiS_2−<i>x</i>Se_<i>x</i> system

Abstract

We have studied the local structure of LaO_0.5F_0.5BiS_2-x Se _x by Bi L₁-edge extended x-ray absorption fine structure (EXAFS). We find a significant effect of Se substitution on the local atomic correlations with a gradual elongation of average in-plane Bi-S bondlength. The associated mean square relative displacement, measuring average local distortions in the BiS₂ plane, hardly shows any change for small Se substitution, but decreases significantly for [Formula: see text]. The Se substitution appears to suppress the local distortions within the BiS₂ plane that may optimize in-plane orbital hybridization and hence the superconductivity. The results suggest that the local structure of the BiS₂-layer is one of the key ingredients to control the physical properties of the BiS₂-based dichalcogenides.