Palladium-catalysed direct arylation of heteroarenes using 1-(bromophenyl)-1,2,3-triazoles as aryl source

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

Joanna Wencel‐Delord, Frank Glorius · Nature Chemistry · 2013 · 2.4K citations

Pharmacy, Chemistry, Structure-activity Relationships +13

Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates

Fabio Bellina, Renzo Rossi · Tetrahedron · 2009 · 556 citations

Natural Sciences, Chemistry, Medicinal Chemistry +16

Cross‐Coupling of Heteroarenes by CH Functionalization: Recent Progress towards Direct Arylation and Heteroarylation Reactions Involving Heteroarenes Containing One Heteroatom

Renzo Rossi, Fabio Bellina, Marco Lessi et al. · Advanced Synthesis & Catalysis · 2014 · 438 citations · Full text

Natural Sciences, Chemistry, Medicinal Chemistry +17

Assisted Ruthenium-Catalyzed C−H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents

Lutz Ackermann, R. Vicente, Andreas Althammer · Organic Letters · 2008 · 392 citations

Natural Sciences, Chemistry, Catalysis +9

Palladium‐Catalyzed Direct Arylations of Heteroarenes with Tosylates and Mesylates

Lutz Ackermann, Andreas Althammer, Sabine Fenner · Angewandte Chemie International Edition · 2008 · 336 citations

Natural Sciences, Chemistry, Catalysis +16