Concepedia

Palladium‐Catalyzed Direct Arylations of Heteroarenes with Tosylates and Mesylates

Lutz Ackermann, Andreas Althammer, Sabine Fenner

Angewandte Chemie International Edition · 2008 · 336 citations · 34 references

DOI

Concepts

Abstract

A toss up: A highly active palladium complex enabled the first direct arylation of heteroarenes through CH bond functionalization using tosylates or mesylates as electrophiles with ample scope.

References

34

Palladium‐Catalyzed Cross‐Coupling Reactions in Total Synthesis

K. C. Nicolaou, Paul G. Bulger, David Šarlah · Angewandte Chemie International Edition · 2005 · 2.7K citations

, , +6

Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands

Rubén Martı́n, Stephen L. Buchwald · Accounts of Chemical Research · 2008 · 2.6K citations

, , +15

Atom Economy—A Challenge for Organic Synthesis: Homogeneous Catalysis Leads the Way

Barry M. Trost · Angewandte Chemie International Edition in English · 1995 · 2.6K citations

, , +16

Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates

Serge I. Gorelsky, David Lapointe, Keith Fagnou · Journal of the American Chemical Society · 2008 · 1K citations

, , +12

Click Chemistry: Versatility and Control in the Hands of Materials Scientists

Himabindu Nandivada, Xiaoman Jiang, Joerg Lahann · Advanced Materials · 2007 · 697 citations · Full text

, , +13