Physical Chemistry Chemical Physics · 2016 · 112 citations · 67 references
Natural SciencesMaterials EngineeringMaterials ScienceCeramic MaterialsElectronic MaterialsThin FilmsFatigueFerroelectric CeramicsFerroelectric MaterialsRare-earth-doped MaterialsThin Film Mechanical PropertiesFerroelectric Thin FilmsPulsed Laser DepositionPulsed Laser Deposition CoatingsThin Film FerroelectricsThin Oxide Films
based ferroelectric devices is fatigue. So far, there have been a few studies on the fatigue mechanism of this material. Here, we report a systematic study of the fatigue mechanism of yttrium-doped hafnium oxide (HYO) ferroelectric thin films deposited by pulsed laser deposition. The influence of pulse width, pulse amplitude and temperature on the fatigue behavior of HYO during field cycling is studied. The temperature dependent conduction mechanism is characterized after different fatigue cycles. Domain wall pinning caused by carrier injection at shallow defect centers is found to be the major fatigue mechanism of this material. The fatigued device can fully recover to the fatigue-free state after being heated at 90 °C for 30 min, confirming the shallow trap characteristic of the domain wall pinning defects.
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