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Switching Reaction Pathways of Benzo[<i>b</i>]thiophen-3-yllithium and Benzo[<i>b</i>]furan-3-yllithium Based on High-resolution Residence-time and Temperature Control in a Flow Microreactor
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Citations
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References
2011
Year
EngineeringFlow CellTemperature ControlChemical EngineeringAppropriate Residence-timeMicroscale SystemThermodynamicsMicrofluidicsBiophysicsFlow ChemistryAbstract Reaction-pathway ControlFlow SynthesisHigh-resolution Residence-timeMultiphase ProcessingMicrofabricationProcess ControlChemical KineticsFlow MicroreactorFlow Microreactor Systems
Abstract Reaction-pathway control of benzo[b]thiophen-3-yllithium and benzo[b]furan-3-yllithium was accomplished in flow microreactor systems. We could switch between the reaction with an electrophile before ring-opening and that after ring-opening at will by choosing an appropriate residence-time and temperature.
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