Inorganic Chemistry · 2010 · 87 citations · 37 references
Natural SciencesChemistryPhysicsCondensed Matter PhysicsMagnetic MaterialsSolid-state ChemistryCluster ChemistryExchange InteractionsFerromagnetismMagnetic Properties Of SolidsMagnetism In SolidsMagnetism Of Inorganic CompoundsLanthanide Single-molecule MagnetsMagnetic Exchange In Transition Metal CompoundsMagnetic Exchange InteractionsMagnetic Properties Of ClustersMagnetism Of Transition Metal ComplexesMolecular MagnetismSingle-molecule MagnetismSingle-molecule Magnets
Through the combination of Sm(III) spin carriers with a Fe(III) system, the largest Fe-Ln cluster so far has been synthesized. To our knowledge, the new complex, Fe(12)Sm(4), is the first Sm(III) single-molecule magnet. Furthermore, Fe(12)La(4) and Fe(12)Gd(4) have also been synthesized to help understand the magnetic exchange interactions and origin of magnetic anisotropy in Fe(12)Sm(4).
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Molecular spintronics using single-molecule magnets
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Macroscopic quantum tunnelling of magnetization in a single crystal of nanomagnets
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