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Rate constants for the reactions of OH radicals with 1- and 2-bromopropane
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1996
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EngineeringLaser ApplicationsLaser AblationOrganic ChemistryChemistryTemperature RangeChemical EngineeringLaser Induced FluorescenceReaction IntermediatePhotophysical PropertyPhysicsPhotochemistryMechanistic PhotochemistryRadical (Chemistry)Laser PhotochemistryNatural SciencesLaser-induced BreakdownOh RadicalsReaction ProcessChemical KineticsRate Constants
The pulsed laser photolysis - laser induced fluorescence (PLP-LIF) method has been used to measure the rate constants for the reactions of OH with 1-bromopropane (CH3CH2CH2Br), k1, and 2-bromopropane (CH3CHBrCH3), k2. The results obtained in the temperature range (233-372) K are :