A new synthesis of .ALPHA.-glycosidically-linked disaccharides using 2.ALPHA.-chloro-3.BETA.-phenylthio KDO derivatives.

Kiyoshi Ikeda, Seijiro Akamatsu, Kazuo Achiwa

Chemical and Pharmaceutical Bulletin · 1990 · 16 citations · 0 references

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Abstract

Stereoselective α-glycosidation was achieved using 2α-chloro-3β-phenylthio KDO having an axial neighbouring group at C-3 which was easily removed later.