Chemical Communications · 2016 · 26 citations · 30 references
Natural SciencesChemistryPhysicsSpectroscopic AnalysisSpectroscopyMagnetic Resonance ImagingMagnetic Resonance Pulse SequencesMagnetic Resonance Signal FormationMagnetic Resonance SpectroscopyBroadband MeasurementBroadband SpectroscopyDiffusion MeasurementsDiffusion Nmr SpectroscopyDiffusion Ordered SpectroscopyPulse Sequence Design
A new pulse sequence, CHORUS Oneshot, allows measurements of diffusion-ordered spectroscopy (DOSY) spectra over the full chemical shift range of (19)F for the first time. Swept-frequency pulses are used to give very broadband excitation; the sequence is a prototype for a large family of very broadband liquid state NMR methods.
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